The
Anti-Reflection coatings course, which follows, begins with a brief
history, then goes on to discuss the Patient benefits of AR. It
continues with a description of some technical aspects such as Constructive
and Destructive Interference, and then provides an overview of the
current technologies and equipment used in the actual AR coating
process.
The
second part of the course describes in-office techniques that should
be used to help prepare lenses for the AR coating process and includes
tips for cutting and edging lenses as well as the use of AR with
certain cosmetic lens treatments such as tinting and edge polishing.
The course concludes with techniques that can be used for effectively
presenting AR coating to Patients.
Much
of the information contained in this course is provided courtesy
of the AR Council. The AR Council is a non-profit industry association,
that was founded in 1989 and is comprised of a variety of companies
with a strong interest in anti-reflective coatings. It promotes
the use of anti-reflective coatings on eyewear through education,
marketing, public relations and advertising.
Anti-Reflection Lens Coating Overview


AR improves a Patient's appearance by making
their lenses appear to
be virtually invisible by reducing the glare on the surface of the
lenses.
And the Patient's vision is improved due to the transmission of
more light.
The
most obvious and demonstrable advantage in the use of an AR coating
is its visual and cosmetic improvement qualities. AR coating reduces
reflections off the front and back surfaces of the lens that allow
many people to actually see better, especially at night.

From left to right are lenses without
coating, single coated, and multicoated.
From the first to the third image the light
transmission improved from 96% to 99.5%.
Anti-reflective coatings have been popular for many years in Europe
and Asia because of the visual and cosmetic improvements to the
wearer. It is estimated that only about 12-15% of optical prescriptions
in the United States are coated with AR, compared with 65% in Europe
and 95% in Japan. Part of the reason for the relatively low acceptance
in the United States is the popularity of plastic lenses; it is
more difficult to reduce reflections on plastic lenses than it is
on glass. While anti-reflective coatings have obtained a reputation
as being difficult to clean and easy to scratch, recent improvements
in coating and lens technology have begun to overcome these earlier
objections resulting in a more viable product.
It was in 1892 when the principle of “thin film coating”
was first discovered. Dennis Taylor, an English scientist, found
that an older lens that had been oxidized would transmit more light
than a newer lens. The cause of this phenomena was tarnish which
had, with time, accumulated on the lens through oxidation. Taylor
accidentally discovered that the tarnish caused improved light transmittance
through the lens. By 1904, Taylor patented a method for artificially
aging lenses by using a method of chemical treatment.
Forty-three years later modern AR coatings were developed in Germany,
but were held by the government for military reasons until 1939.
The first introduction for ophthalmic purposes didn’t come
until 1957 for the glass market and 1974 for plastic ophthalmic
lenses. This early introduction was in Europe only.
An AR coating is a very thin film. Because it is less than one wave
length of light in thickness it is measured in angstroms, which
is one-tenth of a billionth of a meter. A simple analogy may work
better in understanding a “thin film” coating. Imagine
a plaster wall 150 feet thick with a covering of wallpaper. That
proportion of wallpaper would equal the thin film of AR coating
on the front of a lens 2 mm thick.
Examples of the latest in thin film AR coating


At left a single coated lens using
thin film in the 1950's - 1970's.
At right a more recent lens. Green-purple
reflections means all lenses are multicoated.
AR coated lenses can also significantly improve night driving vision.
The contrast of bright lights from oncoming cars against the blackness
of night increases the incidence of noticeable reflections for the
wearer which can effect visual acuity.


One of the most frequent complaints
of eyeglass wearers is the
"halo" or "starburst" effect from lights at
night. AR significantly reduces
these effects, producing a remarkable improvement in night vision.


This is especially true while driving
at night. Reduced glare from surrounding
lights as well as oncoming headlights enables you to drive more
safely at night.
Anti-reflective coatings are part of a larger family of “thin
film” coatings which can be deposited on a lens or other transparent
media by a process of vacuum deposition. You would not want to buy
a multiple lens system, like those found in microscopes, telescopes,
binoculars or cameras, without an excellent anti-reflective coating
applied. Each lens in the instrument would reduce the light transmitted
to the eye in succession. Thus, the object being viewed would appear
more dimly lit or less bright than it would with AR coating. Multiple
lens systems with AR coatings have been used for years by manufacturers
of quality cameras. Without a good AR coating, “ghost”
images caused by internal reflections, can appear and ruin your
photographs.
General uses of AR coated lenses
Ophthalmic
Optics
Laser
Mirrors
Microscopes
Binoculars
Aircraft
Instruments
Precision
Optics
Cameras
Ophthalmic
optics
Although the reflections most obvious to the observer are seen from
the front surface of the lens, half of the reflections seen by the
observer standing in front of the person wearing the glasses are,
in fact, caused by the rear surface of the lens. Bright objects
to the rear of the wearer will also cause a reflection from the
front and rear surface of the lens to the wearer’s eye.
One of the most common reflections is that of the wearer’s
own eye. These reflections are generated from both the front and
rear surface of the lens and will include the wearer’s eyelashes
and facial skin in the immediate area of the lens. These so-called
“ghost” images are reflected toward the optical center
of a minus lens. Reflections will not exceed more than 8% of the
total light or 4% per surface as a general rule, but represent a
significant number of distractions to which a wearer will be subjected.
These reflections, plus the reduced light transmitted to the eye,
can impact the vision of the wearer.
Only 92% of light entering an uncoated CR-39 lens is transmitted
through the lens; with a multi-layer coating that number increases
to nearly 99.5%. Both sides of a lens should be coated to maximize
efficiency. A multi-layered anti-reflection coating for the lenses
will improve the aesthetics of a high refractive index material
(1.6 or greater) more than CR 39 because high refractive index materials
naturally reflect more light. A material with a refractive index
of 1.6 transmits only about 87% of incident light with 13% lost
to reflections. An anti-reflection coating will increase the percentage
of transmitted light from 87% to 99%. AR coating is also especially
effective with aspheric lenses since the flatter back surfaces tend
to create more back side reflections.


At left an untreated lens displays
glare.
At right an AR coated lens. Light transmission is improved by 4%.
When light enters the lens, a portion of that light is reflected
from the front surface; about 4%. This means that light transmittance
is reduced by 4%. This happens again on the rear surface of the
lens, but for this discussion only the front surface will be considered.
To better understand how AR coating works, lets review the basics
of wave theory. We’ll start with an analogy. Imagine two stones
thrown into a pond or rain drops hitting a puddle. The waves emerging
from two stones or drops of water eventually run into each other
canceling each other out. This is actually the theory of “wave
interference” at work. There is positive or “constructive
interference” and negative or “destructive” interference.
Let’s look at constructive interference with this simple example.
One pile of sand added to another equals a pile twice as high. Add
a pile of sand to a hole in the ground of the same volume and zero
is the result. This is a visual example of destructive interference.
Constructive
Interference
Add two piles of sand together and the result is a pile of sand
twice as high.
Destructive Interference
Add a pile of sand to a hole in the ground of the same volume and
the result is zero.
Anti-Reflection Coating
Technical aspects
Returning
to the light wave, the same principle applies. Add the “plus”
waves together and the height of the new wave doubles. That is constructive
interference. But reverse one of the waves or make a negative image
of it, and then add the plus wave and the minus wave. The result
is zero. That is destructive interference.
Now consider the lens and how this application works to help. Light
waves enter an uncoated lens at obtuse angles causing reflections
on both sides of the lenses. After the AR coating has been applied
only direct light is allowed to pass through the lens. This occurs
because the thickness of the coating is measured precisely in wave
length thickness. To be more precise, it is one quarter of a wavelength.
This means that the waves travels one quarter of its own length
from the front surface of the coating to the front surface of the
lens. Then it travels another quarter of its own length to leave
the surface after being reflected from the front surface of the
lens. This is an important concept if we are to understand how an
anti-reflective coating works. A light wave has now traveled one
half of its own length, thereby reversing itself against the next
one and the one before it. The waves create destructive interference
and cancel each other.
Light
transmission of different lens materials with and without AR coating

Without
AR Without AR Without
AR AR
Since one coating layer is precisely matched to eliminate one wavelength,
other wavelengths (or colors) are not eliminated completely. By
adding additional layers of coatings to the surface, additional
wavelengths can be eliminated. This becomes a complex formula best
completed by computer. Each manufacturer has a formula which is
proprietary and felt to be their edge in this competitive market.
When measured on a spectrophotometer, each of these individually
formulated coatings appear differently and become the AR coating
“fingerprint” of that manufacturer.
Every AR coating exhibits some residual color seen in the reflections
of even a multi-layer coating. The color is significantly less in
a multi-layer coating as compared to a bi-layer coating, however.
The variations in color and intensity sometimes helps to identify
the manufacturer of the coated product.
If a five layer coating is better than a two layer coating, does
that mean that a 20 layer coating would be better still? AR coating
efficiently is not directly improved by the number of layers, so
much as by what each layer contributes to the reduction in reflection.
Once again, the formulation of types and thickness of each material
to be used in the five layer matrix becomes the priority in this
very highly technical area of optics.
In fact, it is only due to refinements in both coating equipment
and computers used to run them that these multi-layer coatings can
be enjoyed by the Patients. The actual process of AR coating has
evolved significantly over the last 50 years and is truly a state-of-the-art
“high tech” process which utilizes a vacuum deposition
technology. Modern AR coating equipment has been known to cost between
$500,000.00 and $1,000,000.00.
Keeping
lenses free of smudges and spots is a daily nuisance.
The process includes a hydrophobic/oleophobic layer applied
to the exterior of both sides of the lenses, which creates a
protective shield that repels water, dirt, dust and even oils.
This super smooth surface helps to keep lenses cleaner.


The photos above are of a drop
of water on top of of two lenses,
one with AR and the other uncoated. Notice how the droplet on
the left actually"beads up" or repels the water as the
surface
tension is removed by the AR coating, while the uncoated
lens on the right actual pulls the water toward the surface
of the lens. The same is true for dust dirt and even oil. Also
notice how the surface of the uncoated lens is much
more visible that that of the uncoated lens.
To begin the coating process, lenses must be carefully inspected
for scratches or surfacing imperfections. Lenses are thoroughly
cleaned to ensure good adhesion of the coating to the surface of
the lens. Sophisticated ultrasonic cleaning processes are used by
most coating companies, which utilize many cleaning and rinse cycles.
Once thoroughly cleaned, the lens is inspected once again to make
sure that it has been properly cleaned (if a wax has been applied
to hide lens imperfections this cleaning will remove the wax, highlight
the scratches and make them more visible after coating). Rejected
lenses will be returned to the lab to be remade.
The lens is placed in a degassing oven to assure that all moisture
has been removed. This is an important step to make the coating
process faster and efficient.
A typical vacuum coating machine has a rotating lens rack at the
top of the unit. A monitoring device measures coating thickness.
The machine actually measures the change in the frequency of an
oscillating quartz crystal. The frequency of the crystal changes
as the coating builds on its surface. Optical monitors can also
be used in some cases. As the coating builds with the oscillating
quartz crystal, the mechanical energy is changed to electrical energy
and is fed into a computer for precise layer thickness. The composition
and formulation of the materials evaporated onto the lens are proprietary.
An electron beam gun evaporates the material to be used in the coating
application. Vaporized molecules travel through the chamber to adhere
to the lens surface. In a multiple layer coating system the computer
controls the time and sequence of the deposition of coatings per
side during operation.
A microscopic view of a typical AR coated surface shows very porous
and bumpy areas in which oils and debris can accumulate on the last
hard AR layer. Lenses seem dirty, oily and smudgy as a result of
this porosity. A significant enhancement to the AR coating process
is the application of an additional layer to fill in this porous
material to provide a smooth, slick surface. This aids in abrasion
resistance and makes the lenses easier to clean than any uncoated
lenses. After the hydrophobic coating application the lenses are
annealed for a tight chemical bond. As many of you know, AR coating
with a hydrophobic coat make the lenses much easier to care for
and as with AR coating–the hydrophobic coating will continue
to be improved.
Preparing
lenses for AR coating
Inspection
and Cleaning
Before being sent to the coating lab, the lenses must be thoroughly
cleaned and inspected in your office. A slight blemish or scratch
which may go unnoticed on an uncoated lens becomes much more visible
once the lens is coated. It’s best to inspect the lenses under
a bright light, such as a halogen lamp, to get an idea what the
lenses will look like after coating.
The lenses are inspected again by the lab, then thoroughly cleaned
with alcohol to remove any markings or dried edger material. In
the coating lab, the lenses are subjected to a series of ultrasonic
baths which make them “raw” so they can accept a base
to which the AR coating can adhere. The lenses are then baked in
an oven to remove any excess moisture, since excessive moisture
can cause adhesion problems. Finally, the lenses are placed in a
vacuum chamber for the coating process where a layer of binding
material, either chromium or silicon monoxide, is applied to the
lens surface.
Know your lenses. Virtually any lens can be AR coated, including
laminates and photochromics. However, AR coating does affect the
changeability of photochromics slightly. Lenses should always be
coated in pairs to avoid slight variations in residual color.
It’s best to provide the coating lab with ample information
about the lenses including, lens material, manufacturer, color,
and any in-office treatments you’ve applied including UV dye.
Tips
for cutting and edging
lenses that are to be AR coated
Organize
edging jobs so that all like materials are cut at the same time,
i.e., don’t cut CR39 after a glass job.
Avoid
cutting plastic lenses on a glass edger.
Wash
you system down with water spray to remove any lens material remaining
on the machine.
Use
separate coolant buckets for glass and plastic jobs.
Be
certain chuck pressure is correct when lenses are edged.
Change
chuck pads when changing material.
Use
surface-saver tape when edging, edge-polishing or grooving then
remove the tape immediately after processing.
Be
sure lenses are free from any kind of edger slurry and that they
are free from layout marks before shipping to the coating lab.
AR coated lenses
Cosmetic considerations
Edge Polishing
Edge polishing should be done before the lenses are coated. Although
the lens edges are not coated, any reflections that come through
the edges are usually minuscule. While edge polishes and AR coating
can work well together, both a polished edge and a frosted sample
should be demonstrated to the Patient.
Tinting
If the lenses are going to be tinted, this must be done before being
sent to the AR lab. Cosmetic tints reduce light transmission slightly,
counteracting the purpose of AR. Coating the lenses makes them virtually
invisible, tints make them visible again. Also, the color may not
exactly match the sample since AR coating has its own residual color.
For best results tint the lenses about 15% darker, then bleach out
the excess color until it is about 5% to 10% darker than the end
result you want. This will remove any surface dye and stabilize
the color. UV treated lenses can also be AR coated. The back surface
of sun lenses are often tinted to minimize reflections from light
coming from the side or back of the wearer.
Selecting
an AR coating laboratory
Lenses can be sent directly to a coating lab or they can be sent
to the surfacing lab who may act as a middleman. The performance
of the lab can be as important as the performance of the coating
since customer service is critical to your success. Any questions
you might have regarding AR coating should be answered quickly and
politely. The cost of having lenses coated will vary according to
the type of lenses being used, whether one side or both is being
coated, and the amount of work the lab does for you.
Most AR coaters provide same day turn-around within their labs,
which means three business days when transportation time is factored
in. The coating lab should be able to provide support in an effort
to educate Patients about the benefits of AR coating, and the Dispenser
with marketing support such as point of purchase materials, and
with the technical aspects of dispensing AR.
Presenting
AR coating
The Refractionist can play an important role in presenting AR coating.
The discussion of AR should begin in the exam room and be seen as
an opportunity to educate Patients on the benefits of AR. Lifestyle
information can be gathered verbally, or when the Patient completes
a questionnaire. Either method can be used as a lead-in to presenting
information about AR coating, or any other premium lens product
such as high index materials or aspheric's. AR coating could be
written on the RX, and it should be worn by the office staff.
After the exam, the Patient should be introduced to the Dispenser
and the Refractionist may explain any lens options that were discussed
with the Patient. If the Patient has selected high index lenses
AR coating is especially important since high index materials reflect
more light than conventional lenses. Many Practitioners coat the
back surface of sunglass lenses to minimize reflections when the
sun is located to the side or behind the Patient’s head. AR
coated photochromics can improve light transmission at night while
reducing back surface reflections.

Demonstration kits can be used when presenting AR coating to the
Patient. The cosmetic benefits of AR can be easily demonstrated
by placing two plano lenses in an attractive frame, one AR coated
and the other not. The Dispenser should place the frame on the Patient
and point out the cosmetic appeal of the coated lens. An especially
effective method of demonstrating improved contrast enhancement
of AR coated lenses is to hold a partially coated lens over printed
material. The coated portion of the lens will produce a sharper
crisper image.
When pricing AR coating, many Practitioners “bundle”
the cost of AR into the lens price and consider it an integral part
of the lens choice.
Provide excellent customer service with personalized attention and
concern for ascertaining the needs of your Patient, then using your
professional expertise to help them fill those needs.
Finally, its important to educate Patients on the proper care and
maintenance of their AR coated lenses. Some suggestions for a Patient
Handout on the care and maintenance of AR coated lenses follows.
Frequently
asked questions about AR coating
Should
AR coating be applied to Transitions lenses?
Yes.
The AR coating creates an oxygen barrier and prolongs the life of
the lens. Normally, without AR coatings the photochromics could
break down as much as 22-23% after two years. With AR coating, the
maximum break down is 16%. There is no loss in speed of activation
and there is minimal-insignificant speed of fade with an AR coating.
Do AR coatings have any UV protection?
No.
AR coatings do not contain any UV protection.
Can lenses be tinted after they have been AR coated?
No.
Tinting needs to be done before the lenses are AR coated.
Patient
handouts are recommended
How
to Take Care of AR Lenses
AR coatings, as they are called, virtually eliminate the reflections,
such as images of your own eyes and eyelashes, from the back sides
of lenses. AR coatings also let more light reach your eyes through
the front side of the lenses, increasing contrast and clarity. This
means that you actually see better - particularly in such low-light
situations as night driving.
AR coating will also significantly reduce light reflections from
the front of lenses, making them seem almost invisible. People will
focus on your eyes, not on your eyeglasses, and when appearing in
photographs or on video, your eyes will become a lot more visible
Clean your new lenses carefully.
Just as your fine jewelry or delicate camera lenses must be cared
for properly, AR coated lenses also need a little TLC so that they
can continue to perform well.
AR
cleaning tips
Rinse
the lenses under the tap with lukewarm water.
Place
a drop of a mild hand soap or dishwashing liquid on each lens. (Dawn
and Joy are ideal. Don’t use soap that contains hand cream
- this will smear the lenses.)
With
your fingers, rub the soap on both sides of each lens for about
5 seconds per lens, then rinse under the tap.
Use
a clean, lint-free cotton towel or a special microfiber cloth available
from your optical dispensary to gently wipe each lens dry. Wash
your microfiber cloths once a week, without a fabric softener to
avoid an accumulation of body oils.
Do
not “polish” your lenses - just remove the water. Avoid
using most tissues or paper towels. Paper products are made from
wood and may contain small particles that can scratch your lenses.
Use care in using any cloths also, because the weave may be rough
enough to scratch the lenses.
Clean
your lenses at least once daily.
When
there’s no water
If you need to clean your AR lenses when you do not have access
to running water, you will need to take certain precautions to ensure
that you do not scratch the lenses:
Use
a spray cleaner that is specially formulated for AR lenses, thoroughly
wetting each side of the lens and wiping them dry with a microfiber
cloth.
Never
attempt to clean your AR lenses dry if there is visible dirt on
them. Rubbing the lenses while they are dirty may scratch them.
If
the lenses are not dirty, only smudged, as with a fingerprint for
example, use the special AR microfiber cleaning cloth to gently
remove the oils.
Common
sense
Use common sense to care for your glasses when you’re not
wearing them to protect your lenses:
Keep
your glasses in their case when they’re not on your face.
If
you remove your glasses from time to time during the day, place
them in their case. If you can’t keep your case handy, be
sure that you do not rest the glasses face-down on the lenses. Also,
keep the temples unfolded (just as they are when you remove them
from your face) so that the temples do not meet the lenses and scratch
them at the contact points.
Rest
the glasses upside down on a flat surface. This will reduce their
chances of tipping over onto the lenses and scratching.

